Triruthenium dodecacarbonyl
Catalog Number
ACM15243331
Synonyms
Ruthenium carbonyl,
tri-Ruthenium dodecacarbonyl
| Description | Atomic number of base material: 44 Ruthenium |
| Molecular Weight | 639.33 |
| Molecular Formula | Ru3(CO)12 |
| Canonical SMILES | [Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+] |
| InChI | 1S/12CO.3Ru/c12*1-2;;;,NQZFAUXPNWSLBI-UHFFFAOYSA-N |
| InChI Key | NQZFAUXPNWSLBI-UHFFFAOYSA-N |
| Purity | Ru ≥25.7% |
| Appearance | orange crystals |
| Application | Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.[5] |
| Storage | room temp |
| Assay | 0.99 |
| EC Number | 239-287-4 |
| MDL Number | MFCD00011209 |
| Packaging | 1, 5, 50 g in glass bottle |
| Quality Level | 100 |