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Tris-(8-hydroxyquinoline)aluminum

Tris-(8-hydroxyquinoline)aluminum
Catalog
ACM2085338-5
CAS
2085-33-8
Synonyms
Aluminum Tris(8-hydroxyquinolinate) (purified by sublimation)
8-Quinolinol Aluminum Complex (purified by sublimation)
Alq3 (purified by sublimation)
DescriptionAlq3 crystals exist in two isomeric states, meridional and facial isomers. A third isomeric state ( γ) was studied by X-ray diffraction, the δ-Alq3 transforms into γ-form at ~180°C. Mechanism of the Alq3 phosphorescence has been studied.
Molecular Weight459.44
Molecular FormulaC27H18AlN3O3
Canonical SMILESO([Al](Oc1cccc2cccnc12)Oc3cccc4cccnc34)c5cccc6cccnc56
InChIInChI=1S/3C9H7NO.Al/c3*11-8-5-1-3-7-4-2-6-10-9(7)8;/h3*1-6,11H;/q;;;+3/p-3
InChI KeyTVIVIEFSHFOWTE-UHFFFAOYSA-K
Melting Point418 °C
Purity>99.0%(T)
AppearanceLight yellow to Amber to Dark green powder to crystal
ApplicationKey green-light emitting and electron transport material for OLEDs.
StorageStore under inert gas
Assay99.995% trace metals basis
EC Number218-227-0
Fluorescenceλex 390 nm; λem 519 nm
FormITO/MoO3/NPD/Alq3/BPhen/LiF/Al[7]• Color: green• Max. Luminance: 20000 Cd/m2• Max. EQE: 1.2 %• Turn-On Voltage: 2.8 V
Gradesublimed grade
MDL NumberMFCD00191693
Orbital EnergyLUMO -3.3 eV
Packaging1, 5 g in glass bottle
Quality Level100

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