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PBDB-T-2Cl

PBDB-T-2Cl
Catalog
ACM2239295715-1
CAS
2239295-71-5
Synonyms
OS0139,PCE 139,PM 7,Poly[[4,8-bis[5-(2-ethylhexyl)-4-chloro-2-thienyl]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]-2,5-thiophenediyl[5,7-bis(2-ethylhexyl)-4,8-dioxo-4H,8H-benzo[1,2-c:4,5-c']dithiophene-1,3-diyl]-2,5-thiophenediyl]
DescriptionBand gap: 1.95 eV
Molecular Formula(C68H76C12O2S8)n
ApplicationHigh-Efficiency Organic Solar Cells (OPVs)Polymeric donor materialLUMO=−3.57 eVHOMO=−5.32 eVOPV Device Performance : PBDB-T-2Cl:IT-4F Voc= 0.86VJsc= 21.46 mA/cm2 FF= 0.75PCE=13.9% PBDB-T-2Cl (or PM7) is a wide bandgap polymer donor (n-type semiconductor) containing chlorinated thienyl benzodithiophene (BDT-2Cl) used in high performance polymer solar cells (PSCs). PBDB-T-2Cl-based devices exhibit higher open circuit voltage (Voc) than the PBDB-T-2F-based devices, due to lower molecular energy levels of PBDB-T-2Cl, and leading to an outstanding power conversion efficiency of over 14%. In general, chlorination is more effective than fluorination in downshifting the molecular energy levels and broadening the absorption spectra.
Storageroom temp
Formparticles
Orbital EnergyHOMO -5.52 eV
Quality Level100

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