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Bis(triphenylphosphine)nickel(II) dichloride

Bis(triphenylphosphine)nickel(II) dichloride
Catalog
ACM14264165
CAS
14264-16-5
Synonyms
Dichlorobis(triphenylphosphine)nickel(II),
NiCl2(PPh3)2,
Nickel(II)bis(triphenylphosphine) dichloride
Descriptiondichloridobis(triphenylphosphane)nickel(II) is a metal phosphine complex with the formula NiCl2[P(C6H5)3]2. It is a dark blue crystalline solid. It is used as a catalyst for organic synthesis.
IUPAC Namedichloronickel;triphenylphosphane
Molecular Weight654.17
Molecular FormulaC36H32Cl2NiP2-
Canonical SMILESCl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2,ZBRJXVVKPBZPAN-UHFFFAOYSA-L
InChI KeyZBRJXVVKPBZPAN-UHFFFAOYSA-L
Melting Point250ºC (dec.)
Flash Point181.7ºC
AppearanceDark gray solid
ApplicationNi(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.
Storageroom temp
Assay99.99% trace metals basis
EC Number238-154-8
Formpowder or crystals
MDL NumberMFCD00009592
Packaging10 g in glass bottle
Quality Level100

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