Bis(triphenylphosphine)nickel(II) dichloride
Catalog Number
ACM14264165
Synonyms
Dichlorobis(triphenylphosphine)nickel(II),
NiCl2(PPh3)2,
Nickel(II)bis(triphenylphosphine) dichloride
Description | dichloridobis(triphenylphosphane)nickel(II) is a metal phosphine complex with the formula NiCl2[P(C6H5)3]2. It is a dark blue crystalline solid. It is used as a catalyst for organic synthesis. |
IUPAC Name | dichloronickel;triphenylphosphane |
Molecular Weight | 654.17 |
Molecular Formula | C36H32Cl2NiP2- |
Canonical SMILES | Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 |
InChI | 1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2,ZBRJXVVKPBZPAN-UHFFFAOYSA-L |
InChI Key | ZBRJXVVKPBZPAN-UHFFFAOYSA-L |
Melting Point | 250ºC (dec.) |
Flash Point | 181.7ºC |
Appearance | Dark gray solid |
Application | Ni(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine. |
Storage | room temp |
Assay | 99.99% trace metals basis |
EC Number | 238-154-8 |
Form | powder or crystals |
MDL Number | MFCD00009592 |
Packaging | 10 g in glass bottle |
Quality Level | 100 |